Tetra-μ2-acetato-bis­{μ2-5-meth­oxy-2-[(2-morpholinoeth­yl)iminio­meth­yl]phenolato}tricadmium(II)

نویسندگان

  • Nooraziah Mohd Lair
  • Hapipah Mohd Ali
  • Seik Weng Ng
چکیده

The central Cd(II) atom in the trinuclear title compound, [Cd(3)(C(14)H(19)N(2)O(3))(2)(CH(3)COO)(4)], lies on a center of inversion and is bonded to the O atoms of four acetate groups as well as to the phenolate O atoms of the mono-deprotonated Schiff base ligands in a distorted all-trans octa-hedral geometry. Two of the acetate groups function in a μ(2)-bridging mode, while the other two each chelate to the terminal Cd(II) atom and simultaneously bind to the central metal atom in a κ(3)-bonding mode. The Schiff base anions N,O-chelate to the terminal metal atoms. The morpholine ring assumes a chair conformation.

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009